Freeman, Benny Ph.D.

Headshot of Professor Benny FreemanRichard B. Curran Centennial Chair in Engineering

Office: CPE 3.404 Mailing Address:
Phone: (512) 232-2803, 232-3810 The University of Texas at Austin
Fax: (512)232-2807 McKetta Department of Chemical Engineering
Email: freeman@che.utexas.edu 200 E Dean Keeton St. Stop C0400
UT Mail: C0400 Austin, TX 78712-1589

Research Areas: Advanced Materials, Polymers & Nanotechnology  and Environmental Engineering

Research Website

Presentation Made to Prospective Graduate Students

Educational Qualifications

Ph.D., Chemical Engineering, University of California, Berkeley (1988)
B.S., Chemical Engineering, NC State University (1983)

NATO Postdoctoral Fellow, Ecole Supérieure de Physique et de Chimie Industrielles de la Ville de Paris, Laboratoire Physico-Chimie Structurale et Macromoléculaire, Paris, France (1988-1989)
Department of Chemical Engineering, NC State University (1989-2002)

Research

My research program explores the relationship between polymer structure, processing and properties. More specifically, we study the effect of polymer structure on the solubility, diffusivity, and permeability of small molecules in polymers and polymer-based materials. These fundamental studies bear directly upon membranes for liquid, gas, and vapor separations; controlled drug delivery devices and techniques; barrier plastics for food and specialty packaging; monomer and solvent removal from formed polymers; and physical aging of glassy polymeric materials and membranes.

Current projects

  • Next Generation Gas Separation Membrane Materials
  • Oxidatively Stable Desalination and Forward Osmosis Membrane Materials
  • Bioinspired Membranes to Control Fouling of Water Purification Membranes
  • Catalytically Active Polymer Membranes for High Barrier Packaging

Awards & Honors

AIChE Clarence (Larry) G. Gerhold Award (2013)
Joe J. King Professional Engineering Achievement Award (2013)
Society of Plastics Engineers’ Lifetime Achievement Award (2013)
Roy W. Tess Award in Coatings (from PMSE Division of ACS 2012)
Member, Editorial Board, Polymer (2011-present)
ACS Award in Applied Polymer Science (2009)
AIChE Institute Award for Excellence in Industrial Gases Technology (2008)
IBM Faculty Award (2008)
Associate Editor, Industrial & Engineering Chemistry Research (2007 – present)
University CO-OP Research Excellence Award for Best Research Paper (2006)
Member, Editorial Board, Journal of Membrane Science (2005 – present)
Member, Editorial Board, Journal of Applied Membrane Science and Technology (2005 – present)
Member, International Editorial Advisory Board, Membrane Journal and Korean Membrane Journal (2003-present)
ACS PMSE Cooperative Research Award in Polymer Science (2001)
Strategic Environmental Research and Development Project of the Year Award (2001)
Fellow of the ACS, AIChE, AAAS, PMSE Division of the ACS, and the IECR Division of the ACS

Selected Publications

  • Miller, D.J., S. Kasemset, D.R. Paul, and B.D. Freeman, “Comparison of Membrane Fouling at Constant Flux and at Constant Transmembrane Pressure,” Journal of Membrane Science, 454, 505-515 (2014).
  • Geise, G.M., D.R. Paul, and B.D. Freeman, “Fundamental Water and Salt Transport Properties in Polymeric Materials,” Progress in Polymer Science, 39, 1-42 (2014).
  • Robeson, L.M., Z.P. Smith, B.D. Freeman and D.R. Paul, “Contributions of Diffusion and Solubility Selectivity to the Upper Bound Analysis for Glassy Gas Separation Membranes,” Journal of Membrane Science, 453, 71-83 (2014).
  • Dreyer, D.R., D.J. Miller, B.D. Freeman, D.R. Paul, and C.W. Bielawski, “Perspectives on Poly(dopamine),” Chemical Science, 4(10), 3796-3802 (2013).
  • Sanders, D.F., Z.P. Smith, R. Guo, L.M. Robeson, J.E. McGrath, D.R. Paul, and B.D. Freeman, “Energy Efficient Polymeric Gas Separation Membranes for a Sustainable Future:  A Review,” Polymer, 54, 4729-4761 (2013).
  • Miller, D.J., X. Huang, H. Li, S. Kasemset, A. Lee, D. Agnihotri, T. Hayes, D.R. Paul, and B.D. Freeman, “Fouling-Resistant Membranes for the Treatment of Flowback Water from Hydraulic Shale Fracturing: a Pilot Study,” Journal of Membrane Science, 437, 265-275 (2013).
  • La, Y.-H., J. Diep, R. Al-Rasheed, D. Miller, L. Krupp, G.M. Geise, A. Vora, B. Davis, M. Nassar, B.D. Freeman, M. McNeil, and G. Dubois, “Enhanced Desalination Performance of Polyamide Bi-layer Membranes Prepared by Sequential Interfacial Polymerization,” Journal of Membrane Science, 437, 33-39 (2013).
  • Geise, G.M., B.D. Freeman, and D.R. Paul, “Sodium Chloride Diffusion in Sulfonated Polymers for Membrane Applications,” Journal of Membrane Science, 427, 186-196 (2013).
  • Geise, G.M., L.P. Falcon, B.D. Freeman, and D.R. Paul, “Sodium Chloride Sorption in Sulfonated Polymers for Membrane Applications,” Journal of Membrane Science, 423-424, 195-208 (2012).
  • Dreyer, D.R., D.J. Miller, B.D. Freeman, D.R. Paul, and C.W. Bielawski, “Elucidating the Structure of Poly(dopamine),” Langmuir, 28, 6428-6435 (2012).
  • Geise, G.M., H.B. Park, A.C. Sagle, B.D. Freeman, and J.E. McGrath, “Water Permeability and Water/Salt Selectivity Tradeoff in Polymers for Desalination,” Journal of Membrane Science, 369(1-2), 130-138 (2011).
  • Wang, H., J.K. Keum, A. Hiltner, E. Baer, B. Freeman, A. Rozanski, and A. Galeski, “Confined Crystallization of Polyethylene Oxide in Nanolayer Assemblies,” Science323, 757-760 (2009).
  • Greenlee, L.F., D.F. Lawler, B.D. Freeman, B. Marrot, and P. Moulin, “Reverse Osmosis Desalination:  Water Sources, Technology and Today’s Challenges,” Water Research, 43(9), 2317-2348 (2009).
  • Park, H.B., B.D. Freeman, Z-B. Zhang, M. Sankir, and J.E. McGrath, “Highly Chlorine-Tolerant Polymers for Desalination,” Angewandte Chemie, 120(32), 6108-6113 (2008).
  • Park, H.B., C.H. Jung, Y.M. Lee, A.J. Hill, S.J. Pas, S.T. Mudie, E. van Wagner, B.D. Freeman, and D.J. Cookson, “Polymers with Cavities Tuned for Fast, Selective Transport of Small Molecules and Ions,” Science, 318, 254-258 (2007).
  • Lin, H., E. van Wagner, B.D. Freeman, L.G. Toy, and R.P. Gupta, “Plasticization-Enhanced H2 Purification Using Polymeric Membranes,” Science, 311(5761), 639-642 (2006).
  • Merkel, T.C., B.D. Freeman, R.J. Spontak, Z. He, I. Pinnau, P. Meakin and A.J. Hill, “Ultrapermeable, Reverse-Selective Nanocomposite Membranes”, Science, 296, 519-522 (2002).
  • K. Nagai, T. Masuda, T. Nakagawa, B.D. Freeman, and I. Pinnau, “Poly[1-(trimethylsilyl)-1-propyne] and Related Polymers: Synthesis, Properties, and Functions,” Progress in Polymer Science, 26, 721-798 (2001).
  • Freeman, B.D., “Basis of Permeability/Selectivity Tradeoff Relations in Polymeric Gas Separation Membranes,” Macromolecules, 32, 375-380 (1999).